There are several issues with the code snippet you posted:
1. The correct syntax of the "subs" function is
In your case, you are calling the function as
which means that in the expression "A", you are trying to replace the variable "s" with "z". However currently there is no "s" in "A", but just "z" and "y". I believe you might be providing the variables "s" and "z" in the wrong order.
2. The bigger issue with this code snippet is that the "subs" function will not accept "s" as an argument in the first place. This is because "s" is not a symbolic or numeric variable, but rather it is a "TF" object. The "subs" function does not support this data type as an input argument.
I am not sure what your ultimate objective is, so I will not be able to offer very specific recommendations. However I believe you should try to change your approach on how you are modeling/representing your system.
For instance, are you trying to first create a symbolic expression using "syms" variables, and then convert it to a transfer function by substituting "s"? This will not be possible by simply using "subs" or any other built-in MATLAB function. However there might be some File Exchange submissions that would let you do this.
Your symbolic expression contains an integral. I believe it might not be possible for you to convert this to an s-domain transfer function object in any case, because integrals (even if they represent distributed delays) are not supported in "TF" objects.
If you are trying to do symbolic operations such as integration, you should probably just use symbolic variables and not try to convert it to a transfer function object. However if you are trying to do some analysis with your transfer function with distributed delays, I would recommend you try to model this system in Simulink and do the analysis there.
I hope this helps.