Pressure-volume isotherms for a Bragg-Williams lattice gas
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The program shows how to plot figure 14.4 page 248 presented in T. L. Hill, An Introduction to Statistical Thermodynamics, Dover, New York, 1986. The Bragg-Williams approximation gives pressure-volume isotherms similar to those obtained using the van der Waals equation and it predicts first-order phase transition. We use the symmetry condition to draw the horizontal stable equilibrium path. We can also use the thermodynamic equal-area theorem as shown at the end of the code.
A similar treatment using Mathematica
can be found at the following link:
Cita come
Housam Binous (2024). Pressure-volume isotherms for a Bragg-Williams lattice gas (https://www.mathworks.com/matlabcentral/fileexchange/18153-pressure-volume-isotherms-for-a-bragg-williams-lattice-gas), MATLAB Central File Exchange. Recuperato .
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- Sciences > Material Sciences > Thermal Analysis >
- Sciences > Chemistry > Chemical Thermodynamics >
- Engineering > Mechanical Engineering > Thermodynamics and Heat Transfer >
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BraggWilliams/
Versione | Pubblicato | Note della release | |
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1.0.0.0 | added link to Wolfram Library Archive |